Cheatography
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The importance of ATP in all living organisms
This is a draft cheat sheet. It is a work in progress and is not finished yet.
Structure and roles of ATP
Adenine triphosphate belongs to a group of molecules called nucleotides. |
It is made from ribose and adenine (ribulose) and 3 phosphates. |
It is the universal energy carrier (used in all reactions in all organisms), and releases energy in small quantities (30.6kJ per mol) via a one-step reaction when the high energy bond between the second and third phosphate group is broken. |
This hydrolysis reaction is hydrolysed by the enzyme ATPase. |
Structure of ATP
When ATP is hydrolysed, it provides energy for a wide range of processes including: protein synthesis, active transport and mitosis. |
Comparison of ATP synthesis in mito and chloro
Features |
Mitochondria |
Chloroplasts |
Mechanism |
Uses energy carried by electrons to pump protons across the membrane, they then flow back through stalked particles |
Uses electron energy to pump protons across the membrane, which then flow back through stalked particles |
Enzyme involved |
ATP synthase |
ATP synthase |
Proton gradient |
From inter-membrane space to matrix |
From thylakoid space to stroma |
Site of electron transport chain |
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Thylakoid membrane |
Co-enzyme involved |
FAD, NAD |
Terminal electron acceptor |
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NAPD and H+ (non-cyclic photophosphorylation) and chlorophyll+ (cyclic photophosphorylation) |
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Structure of mitochondria and chloroplasts
The mitochondria and chloroplast membranes
During photosynthesis and respiration, ATP is made when protons are pumped across membranes using energy from electrons to create an electrochemical or proton gradient. |
When the protons flow back through the stalked particles down the concentration gradient, by a process known as chemiosmosis, ATP synthase phosphorylates ADP into ATP. |
In chloroplasts this occurs on the thylakoid membranes, whereas in mitochondria it occurs on the inner membrane or cristae. |
The electrons pass from the proton pumps to a terminal electron acceptor: in mitochondria this is oxygen, in chloroplasts it is in the coenzyme NADP or chlorophyll. |
Types of phosphorylation
Phosphorylation is the addition of a phosphate group or ion to a molecule. |
In respiration and photosynthesis ADP is the molecule most often phosphorylated, but other molecules can be phosphorylated, e.g. glucose in glycolysis forming glucose diphosphate. |
This makes the glucose more reactive and easier to split as it lowers the activation energy of the reaction involved. |
1. Oxidative phosphorylation. This occurs when a phosphate ion is added to ADP using energy from electron loss i.e. oxidation reactions. |
2. Photophosphorylation. The energy that powers the proton pump and electron transport chain in chloroplasts comes from light, hence ATP in chloroplasts is synthesised by photophosphorylation. |
3. Substrate level phosphorylation. This occurs when phosphate groups are transferred from donor molecules, e.g. phosphate is transferred from glycerate-3-phosphate to ADP in glycolysis of respiration. |
Key Terms
Chemiosmosis |
The flow of protons down an electrochemical gradient, through ATP synthase, coupled with the synthesis of ATP from ADP and a phosphate ion. |
Activation energy |
The energy needed to start a chemical reaction. |
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