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Cheatography

Alkanes Cheat Sheet (DRAFT) by

Chemical Reactions involving alkanes

This is a draft cheat sheet. It is a work in progress and is not finished yet.

Combustion

Reagent
O₂
Complete equation
Alkane + O₂ → CO₂ + H₂O
Incomplete equation
Alkane + 2O₂ → CO + 2H₂O

Synthesis

Hydrog­enation of alkenes and cycloa­lkenes
Reagent
H₂ gas
Conditions
heat / 200°C
 
pressure 50atm
Catalyst
Ni / Pt / Pd
Equation
Alkene + H₂ → Alkane

Cracking (pyrol­ysis)

Large alkanes become smaller alkanes and alkenes
Condition
500°C
Catalyst
Zeolite (SiO₂ - Al₂O₃)
Equation
C₆H₁₄ → C₂H₄ + C₃H₆ + CH₄
 

Haloge­nation

Reagent
Cl₂ / Br₂
Condition
UV light / sunlight
Mechanism
Free radical substi­tution
Rules
Carbon 3° > 2° > 1° > CH₄
 
Equations
Initiation (homol­ysis)
Br₂ → 2Br•
Propag­ation (radical + molecule)
Br• + CH₄ → CH₃• + HBr
 
CH₃• + Br₂ → CH₃Br + Br•
Termin­ation (radical + radical)
Br• + Br• → Br₂
 
Br• + CH₃• → CH₃Br
 
CH₃• + CH₃• → C₂H₆

Haloge­nation