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Cheatography

Chapter 7 Short Answer Cheat Sheet (DRAFT) by

This is a draft cheat sheet. It is a work in progress and is not finished yet.

Describe ionization energy trends:

 
Ionization energy is the minimal energy required to remove an electron from a neutral atom. Since, from left to right, the effective nuclear charge increases, the valence electrons are drawn closer to the nucleus. Hence, it becomes more difficult to extract electrons.

Principles

Aufbau
fill lowest to highest levels with electrons
Hund's
↑ ↑ ↑ and then continue to fill rest of the electrons in
Pauli
not same spin in one orbital

Electron Affinity

 
The energy change that occurs when an electron is added to a gaseous atom or ion
 

Describe the periodic trend for transition metals

 
-atomic size is strongly correlated to Z
eff

-electrons are added to the (n-1)d orbitals and become part of the core electrons which are capable of screening the s valence electrons
-the increase in Z : larger increase in S for the s valence electrons

Why are the electron affinities of 2B > 0?

 
The group 2B metals have complete (n-1)d subshells. An extra electron would occupy the p subshell and be shielded by s and (n-1)d electrons. This is not a lower energy state than the neutral atom and a free electron.