\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{xsgirl99} \pdfinfo{ /Title (313-exam-3.pdf) /Creator (Cheatography) /Author (xsgirl99) /Subject (313 Exam 3 Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{A3A3A3} \definecolor{LightBackground}{HTML}{F3F3F3} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{313 Exam 3 Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{xsgirl99} via \textcolor{DarkBackground}{\uline{cheatography.com/26903/cs/9256/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}xsgirl99 \\ \uline{cheatography.com/xsgirl99} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Published 25th September, 2016.\\ Updated 9th December, 2016.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{2} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Laws}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Zeroth Law: If system x = system y \& system y = system z, then system x = system z. (Transitive)} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{First Law: Internal energy(ΔU) of an isolated system is constant. No heat lost, only transferred.} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Second Law: The entropy of any isolated system always increases.} \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Third Law: The entropy of a system approaches a constant value as the temperature approaches absolute zero.} \tn % Row Count 9 (+ 3) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Cyclic Rule: ({\emph{d}}P/{\emph{d}}T)`v`({\emph{d}}T/{\emph{d}}V)`p`({\emph{d}}V/{\emph{d}}P)`T`= -1} \tn % Row Count 11 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Definitions}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Adiabatic: No transfer of heat or matter} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Diathermal: Heat allowed to transfer, no matter transfer. Can transfer energy in the form of work} \tn % Row Count 3 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Enthalpy(ΔH): Amount of heat content used or released in a system at constant pressure} \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Irreversible: A process that cannot return both the system and the surroundings to their original conditions.} \tn % Row Count 8 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Exam 2}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{ΔU=m`s`/M`s` ΔU`comb`+m`H2O`/M`H2O` C`v,m`(H2O)ΔT+ΔTC`calorimeter`} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{ΔH\textasciicircum{}o\textasciicircum{}=m`salt`/M`salt` ΔH\textasciicircum{}o\textasciicircum{}`solution`+m`H2O`/M`H2O` C`p,m`(H2O)ΔT+ΔTC`calorimeter`} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{S=k ln(W) W=\#of states} \tn % Row Count 5 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Efficiency = 1-|q`cd`|/|q`ab`| \textless{}1} \tn % Row Count 6 (+ 1) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{ΔH\textasciicircum{}o\textasciicircum{}`rt`=ΔH\textasciicircum{}o\textasciicircum{}`298`+∫ΔC`p`(T) dT from 298 to T} \tn % Row Count 8 (+ 2) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{ΔH`combustion` = ΔU`combustion`+Δ(PV)} \tn % Row Count 9 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{For Solids \& Liquids: ΔH\textasciitilde{}= ΔU} \tn % Row Count 10 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{\seqsplit{Δs=-nRln(P`f`/P`i`)+∫nC`pm`/T} dT for P`i` to P`f`} \tn % Row Count 12 (+ 2) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{\seqsplit{Δs=nRln(V`f`/V`i`)+∫nC`vm`/T} dT for V`i` to V`f`} \tn % Row Count 14 (+ 2) % Row 9 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Isolated System: ΔS=q`p`(1/T`1` - 1/T`2`)} \tn % Row Count 15 (+ 1) % Row 10 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Isothermal, Ideal: ΔS=nRln(V`f`/V`i`)} \tn % Row Count 16 (+ 1) % Row 11 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{\seqsplit{ΔS`total`=ΔS+ΔS`surroundings`}} \tn % Row Count 17 (+ 1) % Row 12 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{ΔG=nRT Σ x`i`ln(x`i`) x`i` is mole fraction} \tn % Row Count 18 (+ 1) % Row 13 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{ΔG = TΔS`total`} \tn % Row Count 19 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{3.04 cm} x{4.96 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Internal Energy (ΔU)}} \tn % Row 0 \SetRowColor{LightBackground} General & ΔU=q+w \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} Constant Volume & ΔU=C`v`ΔT = q`v` \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} Adiabatic, Reversible & ΔU= w = n(C`pm`-R)ΔT = nC`vm`ΔT \tn % Row Count 4 (+ 2) % Row 3 \SetRowColor{white} Ideal & ΔU=nC`vm`ΔT \tn % Row Count 5 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{3.52 cm} x{4.48 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Enthalpy (ΔH) (State Fxn)}} \tn % Row 0 \SetRowColor{LightBackground} General & ΔH= ΔU+Δ(PV) = ΔU+nRΔT \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} Constant Pressure & ΔH= C`p`ΔT \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} Ideal & ΔH = q`p` \tn % Row Count 4 (+ 1) % Row 3 \SetRowColor{white} Constant Volume & ΔH= nC`pm`ΔT + VΔP \tn % Row Count 5 (+ 1) % Row 4 \SetRowColor{LightBackground} Even More General & {\emph{d}}H= ({\emph{d}}H/{\emph{d}}P)`T` dT + ({\emph{d}}H/{\emph{d}}T)`P` dP \tn % Row Count 7 (+ 2) % Row 5 \SetRowColor{white} Liquids \& Solids & ({\emph{d}}H/{\emph{d}}P)`T` = V(1-Tβ) \tn % Row Count 9 (+ 2) % Row 6 \SetRowColor{LightBackground} Constant Pressure, closed system & ΔH= \seqsplit{(U`f`+P`f`V`f`)-(U`i`+P`i`V`i`)} \tn % Row Count 11 (+ 2) % Row 7 \SetRowColor{white} Isobaric & ΔH= n∫C`pm`(T) dT = nC`pm`ΔT \tn % Row Count 13 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Exam 2 Material}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{S`m`(T)=S`m`(0\textasciicircum{}o\textasciicircum{}k) +∫C`pm`/T dT(solid 0-T`f`) +ΔH`fus`/T`f` + ∫C`pm`/T dT(liquid T`f`-T`b`) +ΔH`vap`/T`b` ∫C`pm`/T dT(gas T`b`-T) `} \tn % Row Count 3 (+ 3) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{For Ideal Gases: \seqsplit{ΔS`m`=Rln(V`f`/V`i`)=-Rln(P`f`/P`i`)}} \tn % Row Count 5 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{ΔG(T`2`)/T`2`= \seqsplit{ΔG(T`1`)/T`1`+ΔH(T`1`)(1/T`2`-1/T`1`)}} \tn % Row Count 7 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Max Work: Reversible, adiabatic, isothermal} \tn % Row Count 8 (+ 1) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Hess's Law: Total Enthalpy change is independent of \# of steps(path-independent).} \tn % Row Count 10 (+ 2) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{ΔA = ΔU-TΔS = ΔH-nRT (Hemholtz)} \tn % Row Count 11 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{for ΔG\textasciicircum{}o\textasciicircum{}`r` only include non-pure substances.} \tn % Row Count 12 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Exam 3}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{ΔG`R` = ΔG°`R`+RT ln(Q`P`)} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{ln(K`P`) = -ΔG°`R`/RT} \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{K`x`=K`P`(P/P°)\textasciicircum{}-ΔV\textasciicircum{}} \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{dA = 𝛾 dσ gamma is surface tension} \tn % Row Count 4 (+ 1) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Work = 8pi𝛾r dr} \tn % Row Count 5 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Force = 8pi𝛾r} \tn % Row Count 6 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{h(capillary rise/depression) = 2𝛾/𝞺gr} \tn % Row Count 7 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{𝓾`B`=𝓾°`B`+RTln(𝛾{[}B{]}) gamma is activity coefficient} \tn % Row Count 9 (+ 2) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{ΔG`R` = ΔG°`R`-2.303vRT(pH)} \tn % Row Count 10 (+ 1) % Row 9 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{q`x` = kA(T`si`-T`so`)/L} \tn % Row Count 11 (+ 1) % Row 10 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{q''`x`= -k dT/dx = q`x`/A} \tn % Row Count 12 (+ 1) % Row 11 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Ė`in`+Ė`g`-Ė`out` = Ė`internal`} \tn % Row Count 13 (+ 1) % Row 12 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{q`12` = εσA(T`1`\textasciicircum{}4\textasciicircum{}-T`2`\textasciicircum{}4\textasciicircum{}) - Heat xchange via radiation b/t 2 surfaces} \tn % Row Count 15 (+ 2) % Row 13 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{q''`s` = h(T`s`-T`∞`) - Newton's Law of Cooling} \tn % Row Count 16 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}