\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{wburgener} \pdfinfo{ /Title (qualitative-analysis-2-known-unknown.pdf) /Creator (Cheatography) /Author (wburgener) /Subject (Qualitative Analysis 2 Known/Unknown Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{52E841} \definecolor{LightBackground}{HTML}{F4FDF3} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{Qualitative Analysis 2 Known/Unknown Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{wburgener} via \textcolor{DarkBackground}{\uline{cheatography.com/35954/cs/11309/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}wburgener \\ \uline{cheatography.com/wburgener} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Published 29th March, 2017.\\ Updated 29th March, 2017.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{tabularx}{17.67cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{17.67cm}}{\bf\textcolor{white}{Lab Prep}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Clean beakers and test tubes (make sure small test tubes).} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Grab strips of different colored washi tape for labeling.} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Grab disposable pipettes.} \tn % Row Count 5 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Fill soap and distilled water.} \tn % Row Count 6 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{17.67cm}}{\bf\textcolor{white}{Separation of Quall II ions:}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Separation of Qual II ions done with strong base, NaOH.} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Mn \textasciicircum{}2+\textasciicircum{}, Ni\textasciicircum{}2+\textasciicircum{}, Fe\textasciicircum{}2+\textasciicircum{}. Will precipitate as a Hydroxides.} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Al\textasciicircum{}3+\textasciicircum{} and Zn\textasciicircum{}2+\textasciicircum{} will precipitate soluble Hydroxides.} \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Add 2 mL of original solution to small cleaned test tube. (DO NOT USE 2 mL WHEN DOING UNKNOWN)} \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Add 15 drop of 6M NaOH} \tn % Row Count 9 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Centrifuge and save precipitate and supernate. (Test for incomplete reaction; several drops of 6 M NaOH)} \tn % Row Count 12 (+ 3) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Label supernate "Al \& Zn ions".} \tn % Row Count 13 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Dissolve the precipitate with the minimum amount of concentrated Nitric Acid (HNO3) possible.} \tn % Row Count 15 (+ 2) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{If necessary heat the solution.} \tn % Row Count 16 (+ 1) % Row 9 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Label dissolved, " Mn, Ni, \& Fe ions"} \tn % Row Count 17 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{17.67cm}}{\bf\textcolor{white}{Testing for Mn 2+ Presence}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Add approximatly 1/2 of "Mn, Ni, \& Fe" to a small test tube. (DO NOT USE THAT MUCH IF DOING QUAL II UNKNOWN."} \tn % Row Count 3 (+ 3) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Add solid NaBiO3 in excess to the solution and centrifuge.} \tn % Row Count 5 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Deep purple solution confirms Mn \textasciicircum{}2+\textasciicircum{} ion presence.} \tn % Row Count 7 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{17.67cm}}{\bf\textcolor{white}{Testing for the presence of Fe 3+}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Add remaining 1/2 solution of "Mn, Ni, \& Fe" (DO NOT USE ALL IF DOING QUAL II UNKNOWN"} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Excess ammonia does not react with Mn the addition is to make Fe a brown precipitate and Ni a blue supernate.} \tn % Row Count 5 (+ 3) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Add 5 drops of \$M NH4Cl to the solution} \tn % Row Count 6 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Add concentrated ammonium hydroxide (NH4OH) till it is basic to litmus.} \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Add additional three drops to check for reaction completion.} \tn % Row Count 10 (+ 2) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Centerfuge \& save supernate label for Ni testing} \tn % Row Count 11 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Dissolve percipitate with 6M HCl} \tn % Row Count 12 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Add 5 drops of 0.1M NH4SCN. Presence of blood red color confirms presence of Fe.} \tn % Row Count 14 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{17.67cm}}{\bf\textcolor{white}{Testing for Ni Presence}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Complexing agent (Dimethylglyoxime) reacting specifically with Ni ions} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Using test tube labeled Ni supernate} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Appearance of pinkish red precipitate.} \tn % Row Count 4 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{17.67cm}}{\bf\textcolor{white}{Testing for Al Presence}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Addition of acid breaks down Al \& Zn Hydroxides to ions} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Add HNO3 drop wise to supernated labeled "Zn \& Al ions" solution must be basic to litmus paper.} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Add 5 more drops after that to insure reaction completion.} \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Presence of white cloudy percipitate indicated presence of Al ions.`} \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Centerfuge and save Zn supernate for analysis.} \tn % Row Count 9 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{17.67cm}}{\bf\textcolor{white}{Testing for Zn percipitate}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Addition of 6M HCl to supernate Zn+ until solution is acidic to litmus paper} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Add 3 drop of 0.2M K4{[}Fe(CN)6{]} and stir.} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{17.67cm}}{Centrifuge and discard supernate.} \tn % Row Count 4 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{17.67cm}}{Light green precipitate confirms presence of Zn.} \tn % Row Count 5 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \end{document}