\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{Tana} \pdfinfo{ /Title (0620-chemistry-sulfur.pdf) /Creator (Cheatography) /Author (Tana) /Subject (0620 Chemistry Sulfur Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{A7C9CF} \definecolor{LightBackground}{HTML}{F4F8F9} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{0620 Chemistry Sulfur Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{Tana} via \textcolor{DarkBackground}{\uline{cheatography.com/144948/cs/31852/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}Tana \\ \uline{cheatography.com/tana} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Not Yet Published.\\ Updated 25th April, 2022.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{2} \begin{tabularx}{8.4cm}{p{0.8 cm} p{0.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Sources of sulfur}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{• In it's elemental form underground in USA, Mexico and Poland} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{• Can be made from Sulfides ores} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{• Bi-product of from removal of sulfur from petroleum and natural gas} \tn % Row Count 5 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{p{0.8 cm} p{0.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Uses of sulfur}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{• Making of sulphuric acid (important chemical used in many industries)} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{• Used extensively in making rubber tyres more flexible- vulcanising (rubber tyre is heated with sulfur)} \tn % Row Count 5 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{p{0.8 cm} p{0.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Sulfur dioxide}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{• Made by the direct combination of sulfur with oxygen} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{→ This method is the first stage of manufacture of sulphuric acid} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{S + O₂ → SO₂} \tn % Row Count 5 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{p{0.8 cm} p{0.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Uses of sulfur dioxide}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{• As a bleach in the manufacture of wood pulp for paper} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{• Preservative for foods and drinks by killing bacteria} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{• Sulfites are added to foods and these release sulfur dioxide in acidic conditions} \tn % Row Count 6 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{p{0.8 cm} p{0.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Manufacture of sulphuric acid}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{• Synthesized by the contact process} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{→ Uses sulfur and oxygen from air} \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{→ Is done in three distinct conditions} \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{} \tn % Row Count 3 (+ 0) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{{\bf{Stage 1) Oxidation of sulfur}}} \tn % Row Count 4 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{S + O₂ → SO₂} \tn % Row Count 5 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{{\bf{Stage 2) Oxidation of SO₂ to sulfur trioxide}}} \tn % Row Count 6 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{Catalyst used: V₂O₅} \tn % Row Count 7 (+ 1) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{2SO₂ + O₂ ⇌ 2SO₃} \tn % Row Count 8 (+ 1) % Row 9 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{{\emph{Conditions during stage 2}}} \tn % Row Count 9 (+ 1) % Row 10 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{Temperature 450°C} \tn % Row Count 10 (+ 1) % Row 11 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{→ Reaction is exo so increasing temperature shits equilibrium position to the left therefore, higher the temperature, lower the yield.} \tn % Row Count 13 (+ 3) % Row 12 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{Pressure 2 atm} \tn % Row Count 14 (+ 1) % Row 13 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{→ Increase in pressure shifts equilibrium position to the right (direction of a smaller number of gaseous moles)} \tn % Row Count 17 (+ 3) % Row 14 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{{\bf{Stage 3) Sulfur trioxide is absorbed into solution of sulfuric acid to produce oleum}}} \tn % Row Count 19 (+ 2) % Row 15 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{SO₃ + H₂SO₄ → H₂S₂O₇} \tn % Row Count 20 (+ 1) % Row 16 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{→ Trioxide isn't absorbed into water because a fine mist of sulfuric acid will be produced and this would be difficult to produce and thus, highly dangerous} \tn % Row Count 24 (+ 4) % Row 17 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{→ Oleum is added to water to form concentrated sulfuric acid} \tn % Row Count 26 (+ 2) % Row 18 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{H₂S₂O₇ + H₂O → 2H₂SO₄} \tn % Row Count 27 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{p{0.8 cm} p{0.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Properties of sulfuric acid}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{•It is a strong dibasic acid (two of its hydrogen atoms can be replaced by a metal)} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{•Reacts in a similar way to other acids with metal carbonates, oxides, hydroxides and metals (and ammonia)} \tn % Row Count 5 (+ 3) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{•Concentrated sulfuric acid is corrosive and a powerful oxidizing agent} \tn % Row Count 7 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{•A very powerful dehydrating agent (very good at removing water from other substances} \tn % Row Count 9 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{p{0.8 cm} p{0.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Uses of sulfuric acid}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{{\bf{DIlute}}} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{•Used as a catalyst in many organic reactions} \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{•To clean the surface of metals} \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{{\bf{Concentrated}}} \tn % Row Count 4 (+ 1) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{•Used in car batteries, making phosphate fertilizers, soaps and detergents} \tn % Row Count 6 (+ 2) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{•Used to make acid drain cleaners} \tn % Row Count 7 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{•Used in production of paints and dyes} \tn % Row Count 8 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Sugar and sulfuric acid}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/tana_1650910245_sugar and sulguric acid.png}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{When mixed with sugar, (C₆H₁₂O₆), concentrated H₂SO₄ will remove water molecules and leave behind carbon, producing a tower of pure carbon} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}