\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{Tana} \pdfinfo{ /Title (0620-chemistry-processes.pdf) /Creator (Cheatography) /Author (Tana) /Subject (0620 Chemistry Processes Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{FFBA67} \definecolor{LightBackground}{HTML}{FFF6EC} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{0620 Chemistry Processes Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{Tana} via \textcolor{DarkBackground}{\uline{cheatography.com/144948/cs/31868/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}Tana \\ \uline{cheatography.com/tana} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Not Yet Published.\\ Updated 29th April, 2022.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{tabularx}{17.67cm}{p{1.727 cm} p{1.727 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{17.67cm}}{\bf\textcolor{white}{Haber Process}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{For}}}}} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{• Industrial manufacture of ammonia} \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{Raw materials}}}}} \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{• Nitrogen (fractional distillation of liquid air)} \tn % Row Count 5 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Hydrogen (cracking of hydrocarbons)} \tn % Row Count 6 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{Conditions}}}}} \tn % Row Count 7 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Temperature: 450°C} \tn % Row Count 8 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Low temperature since reaction is exothermic} \tn % Row Count 9 (+ 1) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Pressure: 200 to 300 atm} \tn % Row Count 10 (+ 1) % Row 9 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Favours side with lower gaseous moles (products side)} \tn % Row Count 12 (+ 2) % Row 10 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Catalyst: Iron granules} \tn % Row Count 13 (+ 1) % Row 11 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Granules used as they have high surface area, which helps speed up reaction (save time)} \tn % Row Count 15 (+ 2) % Row 12 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• N₂ and H₂ are continuously added in 1:3} \tn % Row Count 16 (+ 1) % Row 13 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Increases concentration, shifting equilibrium position to the right (increasing yield)} \tn % Row Count 18 (+ 2) % Row 14 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• NH₃ is continuously collected} \tn % Row Count 19 (+ 1) % Row 15 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Decreasing concentration of products shifts equilibrium position to the right (increasing yeild)} \tn % Row Count 21 (+ 2) % Row 16 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{Reaction}}}}} \tn % Row Count 22 (+ 1) % Row 17 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{N₂₍₉₎ + H₂₍₉₎ → 2NH₃ (ΔH= negative, exothermic)} \tn % Row Count 24 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{+ Using higher temperature will reduce yield of NH₃ \newline + Using lower temperature will slow down the rate of reaction too much. \newline + Using higher pressure will make the process too expensive \newline + Using lower pressure will reduce yield of NH₃} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{p{1.727 cm} p{1.727 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{17.67cm}}{\bf\textcolor{white}{Contact process}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{For}}}}} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{• Manufacture of sulfuric acid} \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{Raw materials}}}}} \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{• Oxygen (from air)} \tn % Row Count 4 (+ 1) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Sulfur} \tn % Row Count 5 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{Conditions}}}}} \tn % Row Count 6 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Temperature: 450°C (low temperature)} \tn % Row Count 7 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Reactions is exothermic thus, shifting equilibrium position to the left (higher temperature means lower yield and lower temperature means )} \tn % Row Count 10 (+ 3) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Pressure: 2 atm (high pressure)} \tn % Row Count 11 (+ 1) % Row 9 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Increase in pressure shifts equilibrium position to the right (lower gaseous moles present there)} \tn % Row Count 14 (+ 3) % Row 10 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Catalyst: V₂O₅} \tn % Row Count 15 (+ 1) % Row 11 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ To increase rate of reaction} \tn % Row Count 16 (+ 1) % Row 12 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{Reaction}}}}} \tn % Row Count 17 (+ 1) % Row 13 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{• S + O₂ → SO₂ (oxidation/combustion of sulfur)} \tn % Row Count 19 (+ 2) % Row 14 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• 2SO₂ + O₂ ⇌ 2SO₃ (oxidation/combustion of SO₂ to SO₃)} \tn % Row Count 21 (+ 2) % Row 15 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{• SO₃ + H₂SO₄ → H₂S₂O₇ (sulfur trioxide absorbed to H₂SO₄ to produce oleum)} \tn % Row Count 23 (+ 2) % Row 16 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• H₂S₂O₇ + H₂O → 2H₂SO₄ (oleum added to water to make H₂SO₄)} \tn % Row Count 25 (+ 2) % Row 17 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{{\bf{{\emph{Purification of gases}}}}} \tn % Row Count 26 (+ 1) % Row 18 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{• Takes place after SO₂ is made to purify SO₂ and O₂} \tn % Row Count 28 (+ 2) % Row 19 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Gases are passed through an electrostatic dust precipitator to remove insoluble impurities such as sand} \tn % Row Count 31 (+ 3) \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{17.67cm}{p{1.727 cm} p{1.727 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{17.67cm}}{\bf\textcolor{white}{Contact process (cont)}} \tn % Row 20 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{→ Gases are passed through a scrubber to remove water soluble impurities} \tn % Row Count 2 (+ 2) % Row 21 \SetRowColor{white} \mymulticolumn{2}{x{17.67cm}}{→ Gases are passed through a drying tower to remove moisture} \tn % Row Count 4 (+ 2) % Row 22 \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{→ Gases are passed through an arsenic purifier to remove arsenic impurities} \tn % Row Count 6 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{17.67cm}}{+ Lower temperature not used, rate of reaction will be too slow \newline + Low pressure favors side with more gaseous moles (reactants side in this reaction) \newline + Conditions such as adding the reactants and removing the product continuously are not mentioned as they don't affect the yield significantly \newline + Trioxide is not absorbed into water because it produces a fine mist of sulfuric acid which is difficult to condense and highly dangerous} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \end{document}