\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{rhettbro} \pdfinfo{ /Title (water-ph-buffer.pdf) /Creator (Cheatography) /Author (rhettbro) /Subject (Water,pH,Buffer Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{3B8A3E} \definecolor{LightBackground}{HTML}{F2F7F2} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{Water,pH,Buffer Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{rhettbro} via \textcolor{DarkBackground}{\uline{cheatography.com/133961/cs/27499/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}rhettbro \\ \uline{cheatography.com/rhettbro} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Published 12th April, 2021.\\ Updated 14th April, 2021.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{3} \begin{tabularx}{5.377cm}{x{2.43873 cm} x{2.53827 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{5.377cm}}{\bf\textcolor{white}{Water}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{the solvent for virtually all of biochemistry, \textasciitilde{}70\% of the mass within each cell is water} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{{\bf{Carbon}} has {\bf{four electrons}} in the {\bf{outer shell}} - these hybridise into 4 sp\textasciicircum{}3\textasciicircum{} hybrid orbitals as tetrahedron. If symmetrical, the angle is {\bf{109.28 degrees}}.} \tn % Row Count 6 (+ 4) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{WATER AS A SOLVENT ({\bf{substances}} such as household sugar {\bf{dissolve in water}}, means that their molecules {\bf{separate}} from each other, each becoming {\bf{surrounded}} by water molecules.)} \tn % Row Count 10 (+ 4) % Row 3 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{When a substance dissolves in a liquid, the mixture is termed a {\bf{solution}}.} \tn % Row Count 12 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{The dissolved substance is the {\bf{solute}}, and the liquid that does the dissolving is the {\bf{solvent}}.} \tn % Row Count 15 (+ 3) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{{\bf{Water is an excellent solvent for many substances}} because of its {\bf{polar bonds}}.} \tn % Row Count 17 (+ 2) % Row 6 \SetRowColor{LightBackground} Covalent bond & {\bf{Inside a molecule}} \tn % Row Count 19 (+ 2) % Row 7 \SetRowColor{white} Hydrogen bond & {\bf{between molecules}} \tn % Row Count 21 (+ 2) % Row 8 \SetRowColor{LightBackground} Polar bonds (H2O) & {\bf{uneven charge}} \tn % Row Count 22 (+ 1) % Row 9 \SetRowColor{white} Non-polar bonds (O2) & {\bf{even charge}} \tn % Row Count 24 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{5.377cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{5.377cm}}{\bf\textcolor{white}{Henderson-Hasselbalch equation}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{5.377cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/rhettbro_1618207744_Screenshot 2021-04-12 at 2.08.31 PM.png}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{5.377cm}{x{2.4885 cm} x{2.4885 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{5.377cm}}{\bf\textcolor{white}{pH (potential hydrogen)}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{The {\bf{acidity of a solution}} is defined by the {\bf{concentration of H+ ions}} it possesses.} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} pH scale & {\bf{pH = -log`10`{[}H\textasciicircum{}+\textasciicircum{}{]}}} \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} pure water pH (7) & {\bf{{[}H\textasciicircum{}+\textasciicircum{}{]} = 10\textasciicircum{}-7\textasciicircum{}}} moles/liter \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} {\bf{acids}} & substance, {\bf{proton (H\textasciicircum{}+\textasciicircum{}) donors}} \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} {\bf{bases}} & substance, {\bf{proton acceptors (such as OH\textasciicircum{}-\textasciicircum{})}} \tn % Row Count 11 (+ 3) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{Water can act as both a weak acid and a weak base.} \tn % Row Count 12 (+ 1) % Row 6 \SetRowColor{LightBackground} Acids in an aqueous environment & proton moves from one molecule to the other \tn % Row Count 15 (+ 3) % Row 7 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{pH is a measure of {\bf{acidity (\textless{}7) }}or {\bf{alkalinity (\textgreater{}7).}}} \tn % Row Count 17 (+ 2) % Row 8 \SetRowColor{LightBackground} {\bf{Higher amounts}} of protons in a solution & results in a lower pH (acidic) \tn % Row Count 20 (+ 3) % Row 9 \SetRowColor{white} {\bf{Lower amount }}of protons & results in a higher pH (basic, or alkali) \tn % Row Count 23 (+ 3) % Row 10 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{{\bf{Different Enzymes}} have different {\bf{optimal pH}} according to their environment.} \tn % Row Count 25 (+ 2) % Row 11 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{The {\bf{strength of an acid}} is measured by its {\bf{dissociation constant, Ka.}} The {\bf{larger}} the {\bf{Ka}} the more it {\bf{dissociates}} and the {\bf{stronger the acid}}.} \tn % Row Count 29 (+ 4) % Row 12 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{The {\bf{pH}} of a solution of a {\bf{weak acid}} and {\bf{its conjugate base}} is related to the {\bf{concentration of the acid and base}} and the {\bf{pKa}} by the Henderson-Hasselbalch equation.} \tn % Row Count 33 (+ 4) \end{tabularx} \par\addvspace{1.3em} \vfill \columnbreak \begin{tabularx}{5.377cm}{x{2.4885 cm} x{2.4885 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{5.377cm}}{\bf\textcolor{white}{pH (potential hydrogen) (cont)}} \tn % Row 13 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{When {\bf{ph \textless{} pKa}}, the {\bf{weak acid predominates}}. When {\bf{pH \textgreater{} pKa}}, the {\bf{conjugate base predominates}}.} \tn % Row Count 3 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{5.377cm}{p{0.4977 cm} p{0.4977 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{5.377cm}}{\bf\textcolor{white}{Buffers}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{A solution which pH {\bf{resists}} change upon addition of either small amounts of strong acid or strong base are added.} \tn % Row Count 3 (+ 3) % Row 1 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{{\bf{(consist of a weak acid and its conjugate base)}}} \tn % Row Count 5 (+ 2) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{BUFFER CAPACITY - is related to the concentrations of the weak acid and its conjugate base,} \tn % Row Count 7 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{The greater the concentration of the weak acid and its conjugate base, the greater the buffer capacity.} \tn % Row Count 10 (+ 3) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{5.377cm}}{H`2`PO`4-` / HPO`4`\textasciicircum{}2-\textasciicircum{} is the principal buffer in cells, H`2`CO`3` / HCO\textasciicircum{}3-\textasciicircum{} is an important buffer in blood.} \tn % Row Count 13 (+ 3) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{5.377cm}}{Buffers work because the concentration of the weak acid and base are kept in the narrow window of the titration curve.} \tn % Row Count 16 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{5.377cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{5.377cm}}{\bf\textcolor{white}{Biological Buffer Systems}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{5.377cm}}{Maintenance of intracellular pH is vital to all cells:} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{5.377cm}}{1. Enzyme-catalyzed reactions have optimal pH,} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{5.377cm}}{2. Solubility of polar molecules depends on H-bond donors and acceptors,} \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{5.377cm}}{3. Equilibrium between CO2 gas and dissolved HCO3- depends on pH.} \tn % Row Count 7 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{5.377cm}}{Buffer systems in vivo are mainly based on:} \tn % Row Count 8 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{5.377cm}}{1. Phosphate, concentration in millimolar range,} \tn % Row Count 9 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{5.377cm}}{2. Bicarbonate, important for blood plasma,} \tn % Row Count 10 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{5.377cm}}{3. Histidine, efficient buffer at neutral pH.} \tn % Row Count 11 (+ 1) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{1}{x{5.377cm}}{Buffer systems in vitro are often based on sulfonic acids of cyclic amines:} \tn % Row Count 13 (+ 2) % Row 9 \SetRowColor{white} \mymulticolumn{1}{x{5.377cm}}{HEPES, PIPES, CHES.} \tn % Row Count 14 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}