\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{Marnise} \pdfinfo{ /Title (chem-1c-chapter-19-review.pdf) /Creator (Cheatography) /Author (Marnise) /Subject (CHEM 1C Chapter 19 Review Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{A3A3A3} \definecolor{LightBackground}{HTML}{F3F3F3} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{CHEM 1C Chapter 19 Review Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{Marnise} via \textcolor{DarkBackground}{\uline{cheatography.com/27448/cs/11995/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}Marnise \\ \uline{cheatography.com/marnise} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Not Yet Published.\\ Updated 5th June, 2017.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{2} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Conceptual Questions}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{What is the Big Idea?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}The properties of transitional metals are determined by the splitting of their d-orbitals.} \tn % Row Count 3 (+ 3) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{What is a complex ion?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}Basically a metal combines with a molecule with a lone pair to form a charged species} \tn % Row Count 6 (+ 3) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{What is a counter ion?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}Basically a charged molecule that is not apart of the complex ion. Usually denoted by being outside the brackets} \tn % Row Count 10 (+ 4) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{What is a coordination compound?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}A compound that consist of both counter ions and complex ions} \tn % Row Count 13 (+ 3) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{What is a ligand?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}A group of molecules that have a lone pair in order to bond to a metal} \tn % Row Count 16 (+ 3) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{What is a chelate?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}A type of ligand that can bond on a metal in two or more places} \tn % Row Count 19 (+ 3) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{What determines how big of a gap between the split d-orbitals?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}The strength of the splitting is determined where the ligands lies in the spectrochemical series} \tn % Row Count 24 (+ 5) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{What is the difference between a low spin complex and a high spin one?} \tn \mymulticolumn{1}{x{8.4cm}}{\hspace*{6 px}\rule{2px}{6px}\hspace*{6 px}A high spin complex is the maximum number of unpaired electrons while low spin is the minimum number of unpaired electrons.} \tn % Row Count 29 (+ 5) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{4 cm} x{4 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Structural Isomer vs. Stereo isomerism}} \tn % Row 0 \SetRowColor{LightBackground} Structural Isomerism & Steroisomerism \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} same atoms but different bonds & same bonds different atoms \tn % Row Count 3 (+ 2) % Row 2 \SetRowColor{LightBackground} Coordination:Ligand in coordination compound changes & Geometrical: atoms can assume different arrangements \tn % Row Count 6 (+ 3) % Row 3 \SetRowColor{white} Linkage:If ligand can bond in more than one place, the point of attachment can change & Optical:Mirror image is not identical to molecule \tn % Row Count 11 (+ 5) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{4 cm} x{4 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Ligand Field Theory vs. Crystal Field Theory}} \tn % Row 0 \SetRowColor{LightBackground} Crystal Field Theory & Ligand Field theory \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} Assumes bond is entirely ionic & Assumes both covalent and ionic properties \tn % Row Count 4 (+ 3) % Row 2 \SetRowColor{LightBackground} Better than LE Model because it focuses only on the d-orbitals, which gives the metal its properties & Explains which ligands cause small splitting and which cause large splitting between d-orbitals \tn % Row Count 9 (+ 5) % Row 3 \SetRowColor{white} Explains color and magnetic properties & Closer to pi bond=\textgreater{} weak field \tn % Row Count 11 (+ 2) % Row 4 \SetRowColor{LightBackground} & Closer to pi antibonding =\textgreater{} strong field \tn % Row Count 13 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{p{2.16 cm} x{5.84 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Common Ligand Names}} \tn % Row 0 \SetRowColor{LightBackground} I- & iodo \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} CN- & cyano \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} NH3 & ammine \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} CH3NH2 & methylamine \tn % Row Count 4 (+ 1) % Row 4 \SetRowColor{LightBackground} CO & carbonyl \tn % Row Count 5 (+ 1) % Row 5 \SetRowColor{white} NO & nitrosyl \tn % Row Count 6 (+ 1) % Row 6 \SetRowColor{LightBackground} F- & bromo \tn % Row Count 7 (+ 1) % Row 7 \SetRowColor{white} Cl- & chloro \tn % Row Count 8 (+ 1) % Row 8 \SetRowColor{LightBackground} OH- & hydroxo \tn % Row Count 9 (+ 1) % Row 9 \SetRowColor{white} en & enthylenediamine \tn % Row Count 10 (+ 1) % Row 10 \SetRowColor{LightBackground} ox2- & oxalato \tn % Row Count 11 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}