\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{L\_Wen} \pdfinfo{ /Title (h2-chem-chemical-bonding.pdf) /Creator (Cheatography) /Author (L\_Wen) /Subject (H2 Chem Chemical Bonding Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{0A42A3} \definecolor{LightBackground}{HTML}{EFF3F9} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{H2 Chem Chemical Bonding Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{L\_Wen} via \textcolor{DarkBackground}{\uline{cheatography.com/193987/cs/40409/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}L\_Wen \\ \uline{cheatography.com/l-wen} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Not Yet Published.\\ Updated 22nd September, 2023.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{2} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Chemical Bonding}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 0 (+ 0) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.224 cm} x{1.656 cm} x{2.16 cm} x{2.16 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{Physical Properties}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Melting/} \seqsplit{boiling} point & strength of bonding & amount of energy required to overcome bond & id-id\textless{} pd-pd\textless{} H-bond\textless{} (metallic/ ionic/ covalent) \tn % Row Count 5 (+ 5) % Row 1 \SetRowColor{white} \seqsplit{Solubility} & \seqsplit{favourable} bonds formed? & bonds formed stronger than bonds broken & \tn % Row Count 9 (+ 4) % Row 2 \SetRowColor{LightBackground} & water + polar =\textgreater{} \seqsplit{ion-dipole} & polar + polar & non-polar + non-polar \tn % Row Count 12 (+ 3) % Row 3 \SetRowColor{white} \seqsplit{Electrical} \seqsplit{conductivity} & presence of \seqsplit{electrical} carriers & mobile delocalised e\textasciicircum{}-\textasciicircum{} or ions & \tn % Row Count 16 (+ 4) \hhline{>{\arrayrulecolor{DarkBackground}}----} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.224 cm} x{2.016 cm} x{2.016 cm} x{1.944 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{Covalent Compounds}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{covalent} bonds & EFoA between shared pair of e\textasciicircum{}-\textasciicircum{} and positively charged nuclei & & \tn % Row Count 6 (+ 6) % Row 1 \SetRowColor{white} & dative covalent & one atom \seqsplit{contributes} both bonding e\textasciicircum{}-\textasciicircum{} & \tn % Row Count 10 (+ 4) % Row 2 \SetRowColor{LightBackground} \seqsplit{overlap} or \seqsplit{orbitals} & sigma (σ) bond & head-on overlap & s- and p-orbital \tn % Row Count 14 (+ 4) % Row 3 \SetRowColor{white} & pi (π) bond & side-on overlap & \seqsplit{p-orbitals} only \tn % Row Count 16 (+ 2) % Row 4 \SetRowColor{LightBackground} \seqsplit{Strength} = bond \seqsplit{energy} & no of bonding e\textasciicircum{}-\textasciicircum{} (bond order) & \seqsplit{effectiveness} of orbital overlap & bond polarity (incr ionic \seqsplit{character)} \tn % Row Count 20 (+ 4) % Row 5 \SetRowColor{white} & more bonding e\textasciicircum{}-\textasciicircum{} = stronger EFoA & larger orbital = more diffused = less effective overlap & more polar = stronger EFoA \tn % Row Count 25 (+ 5) % Row 6 \SetRowColor{LightBackground} \seqsplit{simple} \seqsplit{covalent} \seqsplit{structure} & simple discrete molecules & & \tn % Row Count 30 (+ 5) \end{tabularx} \par\addvspace{1.3em} \vfill \columnbreak \begin{tabularx}{8.4cm}{x{1.224 cm} x{2.016 cm} x{2.016 cm} x{1.944 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{Covalent Compounds (cont)}} \tn % Row 7 \SetRowColor{LightBackground} & id id & non-polar; weak & size of electron cloud; \seqsplit{polarisability} \tn % Row Count 4 (+ 4) % Row 8 \SetRowColor{white} & pd pd & polar; stronger than id id & strength of dipole moment \tn % Row Count 7 (+ 3) % Row 9 \SetRowColor{LightBackground} & H bond & H bonded to NOF + lone pair of electrons on NOF & optimal ratio of H:e- (1:1) \tn % Row Count 12 (+ 5) % Row 10 \SetRowColor{white} \mymulticolumn{4}{x{8.4cm}}{giant covalent structure:} \tn % Row Count 13 (+ 1) % Row 11 \SetRowColor{LightBackground} \seqsplit{diamond} & each C bonded to 4 other C atoms & giant covalent lattice & \tn % Row Count 16 (+ 3) % Row 12 \SetRowColor{white} \seqsplit{graphite} & each C bonded to 3 other C atoms & giant extensive planar layers & weak id id between layers \tn % Row Count 19 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}----} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Molecular Shape and Arrangement}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Valence shell electron repulsion theory} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Conditions} \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 2 (+ 0) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 2 (+ 0) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{No of e\textasciicircum{}-\textasciicircum{} pairs} \tn % Row Count 3 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{2} \tn % Row Count 4 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{3} \tn % Row Count 5 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 5 (+ 0) % Row 8 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{4} \tn % Row Count 6 (+ 1) % Row 9 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 6 (+ 0) % Row 10 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 6 (+ 0) % Row 11 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{5} \tn % Row Count 7 (+ 1) % Row 12 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 7 (+ 0) % Row 13 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 7 (+ 0) % Row 14 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 7 (+ 0) % Row 15 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{6} \tn % Row Count 8 (+ 1) % Row 16 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 8 (+ 0) % Row 17 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{} \tn % Row Count 8 (+ 0) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{3.268 cm} x{2.432 cm} x{1.9 cm} } \SetRowColor{DarkBackground} \mymulticolumn{3}{x{8.4cm}}{\bf\textcolor{white}{Electronegativity}} \tn % Row 0 \SetRowColor{LightBackground} tendency of an atom to pull electrons towards itself & nuclear charge & stronger = greater pull \tn % Row Count 4 (+ 4) % Row 1 \SetRowColor{white} & distance of e\textasciicircum{}-\textasciicircum{} from nucleus & further = weaker pull \tn % Row Count 7 (+ 3) % Row 2 \SetRowColor{LightBackground} trend & down group & decrease \tn % Row Count 8 (+ 1) % Row 3 \SetRowColor{white} & across period & increase \tn % Row Count 10 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}---} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.444 cm} x{3.116 cm} x{3.04 cm} } \SetRowColor{DarkBackground} \mymulticolumn{3}{x{8.4cm}}{\bf\textcolor{white}{Ionic compounds}} \tn % Row 0 \SetRowColor{LightBackground} Ionic bond & IMFOA between oppositely charge ions & \tn % Row Count 3 (+ 3) % Row 1 \SetRowColor{white} \seqsplit{structure} & giant ionic lattice structure & \tn % Row Count 5 (+ 2) % Row 2 \SetRowColor{LightBackground} \seqsplit{strength} & lattice energy & (product of charges)/(sum of ionic radius) \tn % Row Count 8 (+ 3) % Row 3 \SetRowColor{white} \seqsplit{coordination} number & number of opp-charged ions surrounding central ion & ligand size increase, coordination number decrease \tn % Row Count 12 (+ 4) \hhline{>{\arrayrulecolor{DarkBackground}}---} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.44 cm} x{1.872 cm} x{1.944 cm} x{1.944 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{IONIC vs COVALENT CHARACTER}} \tn % Row 0 \SetRowColor{LightBackground} Pure \seqsplit{covalent} & Approx equal \seqsplit{electroneg} & no \seqsplit{distortion} of electron cloud & \tn % Row Count 4 (+ 4) % Row 1 \SetRowColor{white} \seqsplit{Covalent} with ionic \seqsplit{character} & atoms with \seqsplit{electroneg} diff & dipole moment (δ\textasciicircum{}+\textasciicircum{}, δ\textasciicircum{}-\textasciicircum{}) & incr \seqsplit{electroneg} diff = incr dipole \tn % Row Count 8 (+ 4) % Row 2 \SetRowColor{LightBackground} Ionic with \seqsplit{covalent} \seqsplit{character} & \seqsplit{polarisation} distorts anion e\textasciicircum{}-\textasciicircum{} cloud & stronger \seqsplit{polarising} power of cation (charge density) & = increase \seqsplit{distortion} = increase covalent character \tn % Row Count 14 (+ 6) % Row 3 \SetRowColor{white} & some form of e\textasciicircum{}-\textasciicircum{} sharing & larger e\textasciicircum{}-\textasciicircum{} cloud = incr \seqsplit{polarisability} & = increase \seqsplit{distortion} = increase covalent character \tn % Row Count 20 (+ 6) % Row 4 \SetRowColor{LightBackground} Pure ionic \seqsplit{character} & complete transfer of e\textasciicircum{}-\textasciicircum{} & e\textasciicircum{}-\textasciicircum{} cloud remains intact and spherical & \tn % Row Count 24 (+ 4) \hhline{>{\arrayrulecolor{DarkBackground}}----} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.368 cm} x{2.16 cm} x{2.16 cm} x{1.512 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{Metallic compounds}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Metallic} bond & EFoA between metallic cations and sea of delocalised, mobile e\textasciicircum{}-\textasciicircum{} & & \tn % Row Count 6 (+ 6) % Row 1 \SetRowColor{white} & in giant metallic lattice structure & & \tn % Row Count 9 (+ 3) % Row 2 \SetRowColor{LightBackground} \seqsplit{Factors} \seqsplit{affecting} \seqsplit{strength} & Charge density & No of e\textasciicircum{}-\textasciicircum{} delocalised per atom & \tn % Row Count 13 (+ 4) % Row 3 \SetRowColor{white} Unique \seqsplit{physical} \seqsplit{properties} & Malleable (beat into sheets) & Ductile (drawn into wire) & orderly \seqsplit{arrangement} of cation \tn % Row Count 17 (+ 4) % Row 4 \SetRowColor{LightBackground} & Alloy formation & non-metal atoms disrupts orderly arrangement & tensile \seqsplit{strength} \seqsplit{increase} \tn % Row Count 21 (+ 4) % Row 5 \SetRowColor{white} & \seqsplit{Reflectivity} & Delocalised e\textasciicircum{}-\textasciicircum{} absorb light and excited & \seqsplit{promoted} to higher level \tn % Row Count 25 (+ 4) % Row 6 \SetRowColor{LightBackground} & & \seqsplit{De-excitation} =\textgreater{} release E & =\textgreater{} light \tn % Row Count 28 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}----} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.8 cm} x{1.8 cm} x{1.8 cm} x{1.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{Special Cases}} \tn % Row 0 \SetRowColor{LightBackground} Anomalous Mr of organic acid in gaseous \seqsplit{phase/benzene} solvent & Apparent Mr twice of anomalous Mr & \seqsplit{dimerisation} & either achieve octet, or due to \seqsplit{favourable} bonds formed (release E) \tn % Row Count 7 (+ 7) % Row 1 \SetRowColor{white} Different physical \seqsplit{properties} of \seqsplit{structural} isomers & 1,2-nitrophenol has lower BP than 1,4-nitrophenol & 1,2-nitrophenol has {\bf{intramolecular}} H-bond & less extensive {\bf{inter-molecular}} H bond \tn % Row Count 13 (+ 6) % Row 2 \SetRowColor{LightBackground} Bp of HI\textgreater{} HBr\textgreater{}HCl & incr in id-id down group & decrease dipole moment down group & incr id-id more \seqsplit{significant} \tn % Row Count 17 (+ 4) % Row 3 \SetRowColor{white} Density of water \textgreater{} ice & ice - hexagonal \seqsplit{arrangement} of water & large amount of empty spaces & \tn % Row Count 21 (+ 4) \hhline{>{\arrayrulecolor{DarkBackground}}----} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}