\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{keeping.it.anon} \pdfinfo{ /Title (chemistry-a-level.pdf) /Creator (Cheatography) /Author (keeping.it.anon) /Subject (Chemistry A-Level Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{C20000} \definecolor{LightBackground}{HTML}{FBEFEF} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{Chemistry A-Level Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{keeping.it.anon} via \textcolor{DarkBackground}{\uline{cheatography.com/208650/cs/44747/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}keeping.it.anon \\ \uline{cheatography.com/keeping-it-anon} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Not Yet Published.\\ Updated 21st October, 2024.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{2} \begin{tabularx}{8.4cm}{x{1.656 cm} x{1.224 cm} x{1.944 cm} x{2.376 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{Transition metal complexes}} \tn % Row 0 \SetRowColor{LightBackground} Complex & Few drops \seqsplit{NaOH/NH3} & Excess NaOH & Excess NH3 \tn % Row Count 3 (+ 3) % Row 1 \SetRowColor{white} pale green {[}Fe(H20)6{]}\textasciicircum{}3+\textasciicircum{} & dirty green \seqsplit{Fe(OH)2} & - & - \tn % Row Count 7 (+ 4) % Row 2 \SetRowColor{LightBackground} \seqsplit{green/violet} {[}Cr(h206{]}\textasciicircum{}3+\textasciicircum{} & pale green \seqsplit{Cr(OH)3} & deep green soln. {[}Cr(OH)6{]}\textasciicircum{}3+\textasciicircum{} & violet soln. {[}Cr(NH3)6{]}\textasciicircum{}3+\textasciicircum{} \tn % Row Count 10 (+ 3) % Row 3 \SetRowColor{white} yellow {[}Fe(H2O)6{]}\textasciicircum{}3+\textasciicircum{} & brown \seqsplit{Fe(OH)2} & - & - \tn % Row Count 13 (+ 3) % Row 4 \SetRowColor{LightBackground} blue {[}Cu(H2O)6{]}\textasciicircum{}2+\textasciicircum{} & pale blue \seqsplit{Cu(OH)2} & - & deep blue soln. {[}Cu(NH3)4(H2O)2{]}\textasciicircum{}2+\textasciicircum{} \tn % Row Count 16 (+ 3) % Row 5 \SetRowColor{white} pale pink {[}Mn(H2O)6{]}\textasciicircum{}2+\textasciicircum{} & light brown \seqsplit{Mn(OH)2} & - & - \tn % Row Count 20 (+ 4) \hhline{>{\arrayrulecolor{DarkBackground}}----} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.52 cm} x{3.192 cm} x{2.888 cm} } \SetRowColor{DarkBackground} \mymulticolumn{3}{x{8.4cm}}{\bf\textcolor{white}{Test for halide ions}} \tn % Row 0 \SetRowColor{LightBackground} Halide ion & Adding HNO3 and AgNO3 & Adding NH3 \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \seqsplit{Chloride} & White ppt & Dissolves in dilute \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} Bromide & Cream ppt & Dissolves in conc. \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} Iodide & Yellow ppt & Doesn't dissolve \tn % Row Count 8 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}---} \SetRowColor{LightBackground} \mymulticolumn{3}{x{8.4cm}}{HNO3 added first to the halide, then AgNO3. This forms a ppt, from which the colour can be used to identify the halide. NH3 is then added if necessary; in dilute ammonia, e.g: only chloride ions dissolves, whereas iodide ions don't dissolve at all.} \tn \hhline{>{\arrayrulecolor{DarkBackground}}---} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{0.912 cm} x{3.344 cm} x{3.344 cm} } \SetRowColor{DarkBackground} \mymulticolumn{3}{x{8.4cm}}{\bf\textcolor{white}{Organic tests (AS)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Alcohols} & Add K2Cr2O7/H+ & Orange to green for 1\textasciicircum{}st\textasciicircum{} and 2\textasciicircum{}nd\textasciicircum{} alcohols \tn % Row Count 3 (+ 3) % Row 1 \SetRowColor{white} \seqsplit{Alkenes} & Add bromine water & Orange to colourless \tn % Row Count 5 (+ 2) % Row 2 \SetRowColor{LightBackground} \seqsplit{Haloalkanes} & Dissolve in ethanol, add water, then do the halide test & \tn % Row Count 9 (+ 4) \hhline{>{\arrayrulecolor{DarkBackground}}---} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.596 cm} x{3.116 cm} x{2.888 cm} } \SetRowColor{DarkBackground} \mymulticolumn{3}{x{8.4cm}}{\bf\textcolor{white}{Organic tests (A-level)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Aldehyde/ketone} & Add 2,4-DNP (Brady's reagent) & Orange ppt forms \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \seqsplit{Aldehyde} & Add Tollen's reagent & Siler mirror forms \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} & Add Fehling's reagent & Red ppt forms \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} \seqsplit{Carboxylic} acid & Add carbonate (same as AS) & CO2 forms \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} & Add PCl5 & Steamy white fumes produced \tn % Row Count 10 (+ 2) % Row 5 \SetRowColor{white} Benzne & Add bromine water (room temp) & no reaction. \tn % Row Count 12 (+ 2) % Row 6 \SetRowColor{LightBackground} & Combustion & Burns with sooty flame \tn % Row Count 14 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}---} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.16 cm} x{5.84 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Radical Substitution}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Conditions} & UV light \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} Bond fission & homolytic (2 radicals formed from covalent bond) \tn % Row Count 3 (+ 2) % Row 2 \SetRowColor{LightBackground} Organic product & haloalkane \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} \seqsplit{Limitations} & further substitution is almost impossible to control, products have to be separated by fractional distillation or chromatography \tn % Row Count 10 (+ 5) % Row 4 \SetRowColor{LightBackground} \seqsplit{INITIATION} & Cl2 -\textgreater{} 2Cl* \tn % Row Count 11 (+ 1) % Row 5 \SetRowColor{white} \seqsplit{PROPOGATION} & CH4 + Cl* -\textgreater{} *CH3 + HCl \tn % Row Count 13 (+ 2) % Row 6 \SetRowColor{LightBackground} & *CH3 + Cl2 -\textgreater{} CH3Cl + Cl* \tn % Row Count 14 (+ 1) % Row 7 \SetRowColor{white} \seqsplit{TERMINATION} & 2Cl* -\textgreater{} Cl2 \tn % Row Count 16 (+ 2) % Row 8 \SetRowColor{LightBackground} & *CH3 +*CH3 -\textgreater{} C2H6 \tn % Row Count 17 (+ 1) % Row 9 \SetRowColor{white} & *CH3 +Cl* -\textgreater{} CH3Cl \tn % Row Count 18 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.56 cm} x{5.44 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Electrophilic Substitution (nitration of benzene)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Reagents/conditions} & conc. HNO3, conc. H2SO4, 50*C \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \seqsplit{Electrophile} & NO2\textasciicircum{}+\textasciicircum{} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} Organic product & nitrobenzene \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} Gen. of electrphile & HNO3 + H2SO4 -\textgreater{} {\bf{NO2\textasciicircum{}+\textasciicircum{}}} + HSO4\textasciicircum{}\_\textasciicircum{} + H2O \tn % Row Count 7 (+ 2) % Row 4 \SetRowColor{LightBackground} Regen. of catalyst & HSO4\textasciicircum{}\_\textasciicircum{} + H\textasciicircum{}+\textasciicircum{} -\textgreater{} {\bf{H2SO4}} \tn % Row Count 9 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.8 cm} x{5.2 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Electrophilic Sub. (chlorination of benzene)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Reagents/conditions} & Cl2, AlCl3 \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} Electrophile & Cl\textasciicircum{}+\textasciicircum{} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} Organic product & chlorobenzene \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} Gen. of electrphile & AlCl3 + Cl2 -\textgreater{} AlCl4\textasciicircum{}-\textasciicircum{} + {\bf{Cl\textasciicircum{}+\textasciicircum{}}} \tn % Row Count 7 (+ 2) % Row 4 \SetRowColor{LightBackground} Regen. of catalyst & AlCl4\textasciicircum{}-\textasciicircum{} + H\textasciicircum{}+\textasciicircum{} -\textgreater{} {\bf{AlCl3}} + HCl \tn % Row Count 9 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.64 cm} x{5.36 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Electrophilic Sub. (acylation of benzene)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Reagents/conditions} & CH3COCl, AlCl3 \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} Electrophile & CH3CO\textasciicircum{}+\textasciicircum{} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} Organic product & phenyl ethanone \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} Gen. of electrphile & AlCl3 + CH3COCl -\textgreater{} AlCl4\textasciicircum{}-\textasciicircum{} + CH3CO\textasciicircum{}+\textasciicircum{} \tn % Row Count 7 (+ 2) % Row 4 \SetRowColor{LightBackground} Regen. of catalyst & AlCl4\textasciicircum{}-\textasciicircum{} + H\textasciicircum{}+\textasciicircum{} -\textgreater{} AlCl3 + HCl \tn % Row Count 9 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.88 cm} x{5.12 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Electrophilic Sub. (alkylation of benzene)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Reagents/conditions} & CH3Cl, AlCl3 \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} Electrophile & CH3\textasciicircum{}+\textasciicircum{} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} Organic product & methyl benzene \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} Gen. of electrphile & CH3Cl + AlCl3 -\textgreater{} CH3\textasciicircum{}+\textasciicircum{} + AlCl4\textasciicircum{}-\textasciicircum{} \tn % Row Count 7 (+ 2) % Row 4 \SetRowColor{LightBackground} Regen. of catalyst & AlCl4\textasciicircum{}-\textasciicircum{} + H\textasciicircum{}+\textasciicircum{} -\textgreater{} AlCl3 + HCl \tn % Row Count 9 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{3.04 cm} x{4.96 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Electrophilic Sub. (bromination of benzene)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Reagents/conditions} & Br2, AlBr3 \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} Electrophile & Br\textasciicircum{}+\textasciicircum{} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} Organic product & bromobenzene \tn % Row Count 4 (+ 1) % Row 3 \SetRowColor{white} Gen. of electrphile & AlBr3 + Br2 -\textgreater{} AlBr4\textasciicircum{}-\textasciicircum{} + Br\textasciicircum{}+\textasciicircum{} \tn % Row Count 6 (+ 2) % Row 4 \SetRowColor{LightBackground} Regen. of catalyst & AlBr4\textasciicircum{}\_\textasciicircum{} + H\textasciicircum{}+\textasciicircum{} -\textgreater{} AlBr3 + HBr \tn % Row Count 8 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{3.12 cm} x{4.88 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Ammonium, NH4+}} \tn % Row 0 \SetRowColor{LightBackground} Add NaOH to test for NH3 & Red litmus paper turns blue if present \tn % Row Count 2 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{3.76 cm} x{4.24 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Carbonate, CO3\textasciicircum{}2-}} \tn % Row 0 \SetRowColor{LightBackground} Add HCl to carbonate solution & CO2 forms. Turns limewater cloudy \tn % Row Count 2 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.68 cm} x{6.32 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Sulphate, SO4\textasciicircum{}2-}} \tn % Row 0 \SetRowColor{LightBackground} Add BaCl2 & White ppt forms if present (BaSO4) \tn % Row Count 2 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Rate equations}} \tn \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Rate = k{[}A{]}\textasciicircum{}m\textasciicircum{}{[}B{]}\textasciicircum{}n\textasciicircum{} \newline % Row Count 1 (+ 1) k = Ae\textasciicircum{}-Ea/RT\textasciicircum{} \newline % Row Count 2 (+ 1) ln k = -Ea/RT + ln A \newline % Row Count 3 (+ 1) k = rate constant \newline % Row Count 4 (+ 1) {[}A{]} = concentration of A \newline % Row Count 5 (+ 1) {[}B{]} = concentration of B \newline % Row Count 6 (+ 1) m = order wrt A \newline % Row Count 7 (+ 1) n = order wrt B \newline % Row Count 8 (+ 1) A = Arrhenius pre-exponential factor \newline % Row Count 9 (+ 1) e = exponential \newline % Row Count 10 (+ 1) Ea = activation energy (kJmol\textasciicircum{}-1\textasciicircum{}) \newline % Row Count 11 (+ 1) T = temperature, K \newline % Row Count 12 (+ 1) R = gas constant (8.314 JK\textasciicircum{}-1\textasciicircum{}mol\textasciicircum{}-1\textasciicircum{}) \newline % Row Count 13 (+ 1) ln = natural log% Row Count 14 (+ 1) } \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Reaction pathways (aliphatic compounds)}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/keeping-it-anon_1729542589_Reaction pathways 1.png}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Conditions and reactants/reagents shown} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.16 cm} x{5.84 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Electrophilic Addition (alkenes)}} \tn % Row 0 \SetRowColor{LightBackground} \seqsplit{Electrophile} & electron pair acceptor \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \seqsplit{Carbocation} & positive ion with electron deficient carbon \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} Bond fission & heterolytic (cation and anion formed from covalent bond) \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} Organic product & haloalkane \tn % Row Count 8 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{! Curly arrows show movement of an electron} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.016 cm} x{2.088 cm} x{1.296 cm} x{1.8 cm} } \SetRowColor{DarkBackground} \mymulticolumn{4}{x{8.4cm}}{\bf\textcolor{white}{Nucleophilic Substitution (haloalkanes)}} \tn % Row 0 \SetRowColor{LightBackground} Reaction & \seqsplit{Reagent/conditions} & \seqsplit{Nucleophile} & Organic product \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} Hydrolysis (NaOH) & hot NaOH(aq) & OH & alcohol \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} NH3 & ethanolic NH3 & - & amine \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} KCN & ethanolic KCN & - & nitrile \tn % Row Count 8 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}----} \SetRowColor{LightBackground} \mymulticolumn{4}{x{8.4cm}}{Nucleophile: electron pair donor \newline Substitution: when an atom or group of atoms is replaced by another \newline Ethanolic: derived from or containing ethanol} \tn \hhline{>{\arrayrulecolor{DarkBackground}}----} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{4.64 cm} x{3.36 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Nucleophilic Addition (carbonyl compounds)}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{{\bf{Reaction with NaBH4}}} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} Reagents/conditions & NaBH4, warmed \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} Reaction type & reduction \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} Nuceophile & H\textasciicircum{}-\textasciicircum{} \tn % Row Count 4 (+ 1) % Row 4 \SetRowColor{LightBackground} Organic product & alcohol \tn % Row Count 5 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{{\bf{Reaction with HCN}}} \tn % Row Count 6 (+ 1) % Row 6 \SetRowColor{LightBackground} Reagents/conditions & HCN \tn % Row Count 7 (+ 1) % Row 7 \SetRowColor{white} Nucleophile & CN\textasciicircum{}-\textasciicircum{} \tn % Row Count 8 (+ 1) % Row 8 \SetRowColor{LightBackground} Organic product & hydroxynitrile \tn % Row Count 9 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Free radical sub. of ozone}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{{\bf{Depletion 1* }}} \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{CFCl3 -{}-UV-\textgreater{} CFCl2* + Cl*} \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Cl* + O3 -\textgreater{} ClO* + O2} \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{ClO* + O -\textgreater{} Cl* + O2} \tn % Row Count 4 (+ 1) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{{\bf{Depletion 2** }}} \tn % Row Count 5 (+ 1) % Row 5 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{N2 + O2 -\textgreater{} 2NO*} \tn % Row Count 6 (+ 1) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{NO* + O3 -\textgreater{} NO2* + O2} \tn % Row Count 7 (+ 1) % Row 7 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{NO2* + O -\textgreater{} NO* + O2} \tn % Row Count 8 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{*due to chlorine radicals from CFC's \newline **due to nitrogen oxide from aircraft engines and lightning} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}