\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{{[}deleted{]}} \pdfinfo{ /Title (chem-231-midterm-1.pdf) /Creator (Cheatography) /Author ({[}deleted{]}) /Subject (Chem 231 Midterm 1 Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{FFA408} \definecolor{LightBackground}{HTML}{FFF9EF} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{Chem 231 Midterm 1 Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{{[}deleted{]}} via \textcolor{DarkBackground}{\uline{cheatography.com/44610/cs/13172/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}{[}deleted{]} \\ \uline{cheatography.com/deleted-44610} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Not Yet Published.\\ Updated 20th October, 2017.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{2} \begin{tabularx}{8.4cm}{x{2 cm} x{6 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Formulas}} \tn % Row 0 \SetRowColor{LightBackground} Formal Charge & FC = electrons around nuclei - (electrons in lone pairs + 1/2 electrons in bonding pairs) \tn % Row Count 3 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Resonance Structure Rules}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{All resonance structures must have same valence electrons} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Octet rule must be obeyed} \tn % Row Count 3 (+ 1) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Nuclei Positions do not change} \tn % Row Count 4 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.444 cm} x{3.8 cm} x{2.356 cm} } \SetRowColor{DarkBackground} \mymulticolumn{3}{x{8.4cm}}{\bf\textcolor{white}{Functional Groups}} \tn % Row 0 \SetRowColor{LightBackground} Alkane & Single Bond & Ethane \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} Alkene & Double Bond & Ethene \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} Alkyne & Triple Bond & Ethyne \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} \seqsplit{Aromatic} & Aromatic ring (3 single bonds, 3 double bonds) & Benzene \tn % Row Count 6 (+ 3) % Row 4 \SetRowColor{LightBackground} \seqsplit{Haloalkane} & Halogen (atom with 3 lone pairs) & \seqsplit{Chloro/Bromo/etc} + ethane \tn % Row Count 9 (+ 3) % Row 5 \SetRowColor{white} \seqsplit{Alcohol} & OH on it's own & Ethanol \tn % Row Count 10 (+ 1) % Row 6 \SetRowColor{LightBackground} Phenol & Aromatic Ring + OH & Phenol \tn % Row Count 11 (+ 1) % Row 7 \SetRowColor{white} Ether & O in the middle of a chain & \seqsplit{Methoxymethane} \tn % Row Count 13 (+ 2) % Row 8 \SetRowColor{LightBackground} Amine & N on it's own & Methanamine \tn % Row Count 14 (+ 1) % Row 9 \SetRowColor{white} \seqsplit{Aldehyde} & Double bonded O on the end with an H & Ethanal \tn % Row Count 16 (+ 2) % Row 10 \SetRowColor{LightBackground} Ketone & Double bonded O on it's own & Propanone \tn % Row Count 18 (+ 2) % Row 11 \SetRowColor{white} \seqsplit{Carboxylic} Acid & Double bonded O with an OH at the end of a chain & Ethanoic acid \tn % Row Count 21 (+ 3) % Row 12 \SetRowColor{LightBackground} Ester & Double bonded O with an O in the chain & Methyl ethanoate \tn % Row Count 23 (+ 2) % Row 13 \SetRowColor{white} Amide & Double bonded O with an N & Ethanamide \tn % Row Count 25 (+ 2) % Row 14 \SetRowColor{LightBackground} \seqsplit{Nitrile} & C triple bonded with N & \seqsplit{Ethanenitrile} \tn % Row Count 27 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}---} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{1.84 cm} x{6.16 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Naming Chain Fragment}} \tn % Row 0 \SetRowColor{LightBackground} Primary & One x attached \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} \seqsplit{Secondary} & Two xs attached \tn % Row Count 2 (+ 1) % Row 2 \SetRowColor{LightBackground} Tertiary & Three xs attached \tn % Row Count 3 (+ 1) % Row 3 \SetRowColor{white} Iso\_\_\_ & CH3-CH (functional group)-CH3 \tn % Row Count 4 (+ 1) % Row 4 \SetRowColor{LightBackground} Sec\_\_\_ & CH3-CH (functional group)-CH2-CH3 \tn % Row Count 6 (+ 2) % Row 5 \SetRowColor{white} Tert\_\_\_ & CH3-CH (CH3)(functional group)-CH3 \tn % Row Count 8 (+ 2) % Row 6 \SetRowColor{LightBackground} 1 Carbon & meth(ane/yl) \tn % Row Count 9 (+ 1) % Row 7 \SetRowColor{white} 2 Carbons & eth() \tn % Row Count 10 (+ 1) % Row 8 \SetRowColor{LightBackground} 3 Carbons & prop() \tn % Row Count 11 (+ 1) % Row 9 \SetRowColor{white} 4 Carbons & but() \tn % Row Count 12 (+ 1) % Row 10 \SetRowColor{LightBackground} 5 Carbons & pent() \tn % Row Count 13 (+ 1) % Row 11 \SetRowColor{white} 6 Carbons & hex() \tn % Row Count 14 (+ 1) % Row 12 \SetRowColor{LightBackground} 7 Carbons & hept() \tn % Row Count 15 (+ 1) % Row 13 \SetRowColor{white} 8 Carbons & oct() \tn % Row Count 16 (+ 1) % Row 14 \SetRowColor{LightBackground} 9 Carbons & non() \tn % Row Count 17 (+ 1) % Row 15 \SetRowColor{white} 10 Carbons & dec() \tn % Row Count 19 (+ 2) % Row 16 \SetRowColor{LightBackground} Radicals & All carbons and hydrogens \tn % Row Count 20 (+ 1) % Row 17 \SetRowColor{white} \seqsplit{Carbocations} & R groups and hydrogens bonded to a carbon \tn % Row Count 22 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{4 cm} x{4 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Rules}} \tn % Row 0 \SetRowColor{LightBackground} pKa & As pKa Decreases Acidity Increases, as pKa increases Basicity decreases. \tn % Row Count 4 (+ 4) % Row 1 \SetRowColor{white} \% S character & Higher s character means electrons are closer to nucleus, therefore energy for acidity is lower \tn % Row Count 9 (+ 5) % Row 2 \SetRowColor{LightBackground} Radical Selectivity (Faster to slower formation) & Tertiary \textgreater{} Secondary \textgreater{} Primary \textgreater{} Methyl \tn % Row Count 12 (+ 3) % Row 3 \SetRowColor{white} Carbocations Selectivity (Faster to slower formation) & Tertiary \textgreater{} Secondary \textgreater{} Primary \textgreater{} Methyl \tn % Row Count 15 (+ 3) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{IUPAC Nomenclature Rules}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Identify longest chain of Carbons - Determines Parent name} \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{IF there are a couple of possible chains of equal length, choose chain with MORE substituents - avoids complex substituents} \tn % Row Count 5 (+ 3) % Row 2 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Number chain so that the substituents have the smallest possible number} \tn % Row Count 7 (+ 2) % Row 3 \SetRowColor{white} \mymulticolumn{1}{x{8.4cm}}{Place substitute names in alphabetical order (ignore all prefixes EXCEPT iso and cyclo)} \tn % Row Count 9 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{No spaces! only hyphens and commas} \tn % Row Count 10 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Bicyclic Compounds}} \tn % Row 0 \SetRowColor{LightBackground} \mymulticolumn{1}{x{8.4cm}}{Start numbering at bridgehead - go around longest/biggest bridge first} \tn % Row Count 2 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}