\documentclass[10pt,a4paper]{article} % Packages \usepackage{fancyhdr} % For header and footer \usepackage{multicol} % Allows multicols in tables \usepackage{tabularx} % Intelligent column widths \usepackage{tabulary} % Used in header and footer \usepackage{hhline} % Border under tables \usepackage{graphicx} % For images \usepackage{xcolor} % For hex colours %\usepackage[utf8x]{inputenc} % For unicode character support \usepackage[T1]{fontenc} % Without this we get weird character replacements \usepackage{colortbl} % For coloured tables \usepackage{setspace} % For line height \usepackage{lastpage} % Needed for total page number \usepackage{seqsplit} % Splits long words. %\usepackage{opensans} % Can't make this work so far. Shame. Would be lovely. \usepackage[normalem]{ulem} % For underlining links % Most of the following are not required for the majority % of cheat sheets but are needed for some symbol support. \usepackage{amsmath} % Symbols \usepackage{MnSymbol} % Symbols \usepackage{wasysym} % Symbols %\usepackage[english,german,french,spanish,italian]{babel} % Languages % Document Info \author{bubblysoul} \pdfinfo{ /Title (benzenes.pdf) /Creator (Cheatography) /Author (bubblysoul) /Subject (Benzenes Cheat Sheet) } % Lengths and widths \addtolength{\textwidth}{6cm} \addtolength{\textheight}{-1cm} \addtolength{\hoffset}{-3cm} \addtolength{\voffset}{-2cm} \setlength{\tabcolsep}{0.2cm} % Space between columns \setlength{\headsep}{-12pt} % Reduce space between header and content \setlength{\headheight}{85pt} % If less, LaTeX automatically increases it \renewcommand{\footrulewidth}{0pt} % Remove footer line \renewcommand{\headrulewidth}{0pt} % Remove header line \renewcommand{\seqinsert}{\ifmmode\allowbreak\else\-\fi} % Hyphens in seqsplit % This two commands together give roughly % the right line height in the tables \renewcommand{\arraystretch}{1.3} \onehalfspacing % Commands \newcommand{\SetRowColor}[1]{\noalign{\gdef\RowColorName{#1}}\rowcolor{\RowColorName}} % Shortcut for row colour \newcommand{\mymulticolumn}[3]{\multicolumn{#1}{>{\columncolor{\RowColorName}}#2}{#3}} % For coloured multi-cols \newcolumntype{x}[1]{>{\raggedright}p{#1}} % New column types for ragged-right paragraph columns \newcommand{\tn}{\tabularnewline} % Required as custom column type in use % Font and Colours \definecolor{HeadBackground}{HTML}{333333} \definecolor{FootBackground}{HTML}{666666} \definecolor{TextColor}{HTML}{333333} \definecolor{DarkBackground}{HTML}{FFA8A8} \definecolor{LightBackground}{HTML}{FFF4F4} \renewcommand{\familydefault}{\sfdefault} \color{TextColor} % Header and Footer \pagestyle{fancy} \fancyhead{} % Set header to blank \fancyfoot{} % Set footer to blank \fancyhead[L]{ \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{C} \SetRowColor{DarkBackground} \vspace{-7pt} {\parbox{\dimexpr\textwidth-2\fboxsep\relax}{\noindent \hspace*{-6pt}\includegraphics[width=5.8cm]{/web/www.cheatography.com/public/images/cheatography_logo.pdf}} } \end{tabulary} \columnbreak \begin{tabulary}{11cm}{L} \vspace{-2pt}\large{\bf{\textcolor{DarkBackground}{\textrm{Benzenes Cheat Sheet}}}} \\ \normalsize{by \textcolor{DarkBackground}{bubblysoul} via \textcolor{DarkBackground}{\uline{cheatography.com/146556/cs/31742/}}} \end{tabulary} \end{multicols}} \fancyfoot[L]{ \footnotesize \noindent \begin{multicols}{3} \begin{tabulary}{5.8cm}{LL} \SetRowColor{FootBackground} \mymulticolumn{2}{p{5.377cm}}{\bf\textcolor{white}{Cheatographer}} \\ \vspace{-2pt}bubblysoul \\ \uline{cheatography.com/bubblysoul} \\ \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Cheat Sheet}} \\ \vspace{-2pt}Not Yet Published.\\ Updated 26th April, 2022.\\ Page {\thepage} of \pageref{LastPage}. \end{tabulary} \vfill \columnbreak \begin{tabulary}{5.8cm}{L} \SetRowColor{FootBackground} \mymulticolumn{1}{p{5.377cm}}{\bf\textcolor{white}{Sponsor}} \\ \SetRowColor{white} \vspace{-5pt} %\includegraphics[width=48px,height=48px]{dave.jpeg} Measure your website readability!\\ www.readability-score.com \end{tabulary} \end{multicols}} \begin{document} \raggedright \raggedcolumns % Set font size to small. Switch to any value % from this page to resize cheat sheet text: % www.emerson.emory.edu/services/latex/latex_169.html \footnotesize % Small font. \begin{multicols*}{2} \begin{tabularx}{8.4cm}{x{2.08 cm} x{5.92 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Halogenation (substitution)}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & Cl₂ / Br₂ \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} {\bf{Catalyst}} & AlCl₃ / FeCl₃ \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} & {\emph{catalyst produce electrophile}} \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} {\bf{Equation}} & C₆H₆ + Cl₂ → C₆H₅Cl + HCl \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} {\bf{Mechanism}} & free radical substitution \tn % Row Count 10 (+ 2) % Row 5 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{\{\{nl\}\}} \tn % Row Count 11 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{{\bf{{\emph{Formation of halonium ion}}}}\{\{ac\}\}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.16 cm} x{5.84 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Halogenation (addition)}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & Cl₂ / Br₂ \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} {\bf{Condition}} & UV light \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} {\bf{Equation}} & C₆H₆ + 3Cl₂ → C₆H₆Cl₆ \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} {\bf{Mechanism}} & free radical addition reaction \tn % Row Count 8 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2 cm} x{6 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Friedel-Craft Acylation}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & RCOCl (acyl chloride) \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} {\bf{Condition}} & heat / 80°C \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} {\bf{Catalyst}} & AlCl₃ / FeCl₃ \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} & {\emph{catalyst produce electrophile}} \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} {\bf{Mechanism}} & electrophilic substitution \tn % Row Count 10 (+ 2) % Row 5 \SetRowColor{white} {\bf{Equation}} & C₆H₆ + RCOCl → RCOC₆H₅ + HCl \tn % Row Count 12 (+ 2) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{\{\{nl\}\}} \tn % Row Count 13 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2 cm} x{6 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Halogenation of alkylbenzene (UV light)}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & Cl₂ / Br₂ \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} {\bf{Condition}} & UV light \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} {\bf{Mechanism}} & free radical substitution \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} {\bf{Equation}} & (CH₃)C₆H₅ + X₂ → (CH₂X)C₆H₅ + HX \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{\{\{nl\}\}} \tn % Row Count 9 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{reaction occur in alkyl part\{\{ac\}\}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Nitration}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/bubblysoul_1650287201_Chapter 4 Benzene-20.jpg}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Friedel-Craft Alkylation}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/bubblysoul_1650287253_Chapter 4 Benzene-21.jpg}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Hydrogenation}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/bubblysoul_1650287289_Chapter 4 Benzene-23.jpg}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.4 cm} x{5.6 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Nitration}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & HNO₃ \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} {\bf{Condition}} & 55°C \tn % Row Count 3 (+ 2) % Row 2 \SetRowColor{LightBackground} {\bf{Catalyst}} & {\bf{concentrated}} H₂SO₄ \tn % Row Count 4 (+ 1) % Row 3 \SetRowColor{white} & {\emph{catalyst produce electrophile}} \tn % Row Count 6 (+ 2) % Row 4 \SetRowColor{LightBackground} {\bf{Mechanism}} & electrophilic substitution \tn % Row Count 8 (+ 2) % Row 5 \SetRowColor{white} {\bf{Equation}} & C₆H₆ + HNO₃ → C₆H₅NO₂ \tn % Row Count 10 (+ 2) % Row 6 \SetRowColor{LightBackground} {\bf{Observation}} & yellowish oil with almond smell \tn % Row Count 12 (+ 2) % Row 7 \SetRowColor{white} \mymulticolumn{2}{x{8.4cm}}{\{\{nl\}\}} \tn % Row Count 13 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{{\bf{{\emph{Formation of nitronium ion}}}}\{\{ac\}\}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.32 cm} x{5.68 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Friedel-Craft Alkylation}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & RX \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} {\bf{Condition}} & room temperature \tn % Row Count 3 (+ 2) % Row 2 \SetRowColor{LightBackground} {\bf{Catalyst}} & AlX₃ / FeX₃ \tn % Row Count 5 (+ 2) % Row 3 \SetRowColor{white} & {\emph{catalyst produce electrophile}} \tn % Row Count 7 (+ 2) % Row 4 \SetRowColor{LightBackground} {\bf{Mechanism}} & electrophilic substitution \tn % Row Count 9 (+ 2) % Row 5 \SetRowColor{white} {\bf{Equation}} & C₆H₆ + RX → C₆H₅R + HX \tn % Row Count 11 (+ 2) % Row 6 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{\{\{nl\}\}} \tn % Row Count 12 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{X : halogen (Cl₂ / Br₂) \{\{ac\}\}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2.32 cm} x{5.68 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Hydrogenation}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & H₂ gas \tn % Row Count 1 (+ 1) % Row 1 \SetRowColor{white} {\bf{Condition}} & Pt, room temperature \tn % Row Count 3 (+ 2) % Row 2 \SetRowColor{LightBackground} & Ni, 150°C \tn % Row Count 4 (+ 1) % Row 3 \SetRowColor{white} {\bf{Equation}} & C₆H₆ + 3H₂ → C₆H₁₂ \tn % Row Count 6 (+ 2) \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{x{2 cm} x{6 cm} } \SetRowColor{DarkBackground} \mymulticolumn{2}{x{8.4cm}}{\bf\textcolor{white}{Halogenation of alkylbenzene (catalyst)}} \tn % Row 0 \SetRowColor{LightBackground} {\bf{Reagent}} & Cl₂ / Br₂ \tn % Row Count 2 (+ 2) % Row 1 \SetRowColor{white} {\bf{Catalyst}} & AlX₃ / FeX₃ \tn % Row Count 4 (+ 2) % Row 2 \SetRowColor{LightBackground} {\bf{Mechanism}} & electrophilic substitution \tn % Row Count 6 (+ 2) % Row 3 \SetRowColor{white} {\bf{Equation}} & (CH₃)C₆H₅ + X₂ → (CH₃)C₆H₄X + HX \tn % Row Count 8 (+ 2) % Row 4 \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{\{\{nl\}\}} \tn % Row Count 9 (+ 1) \hhline{>{\arrayrulecolor{DarkBackground}}--} \SetRowColor{LightBackground} \mymulticolumn{2}{x{8.4cm}}{reaction occur in benzene ring\{\{ac\}\}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}--} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Halogenation}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/bubblysoul_1650287033_Chapter 4 Benzene-19.jpg}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Friedel-Craft Acylation}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/bubblysoul_1650287268_Chapter 4 Benzene-22.jpg}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} \begin{tabularx}{8.4cm}{X} \SetRowColor{DarkBackground} \mymulticolumn{1}{x{8.4cm}}{\bf\textcolor{white}{Halogenation of alkylbenzene}} \tn \SetRowColor{LightBackground} \mymulticolumn{1}{p{8.4cm}}{\vspace{1px}\centerline{\includegraphics[width=5.1cm]{/web/www.cheatography.com/public/uploads/bubblysoul_1650287308_Chapter 4 Benzene-24.jpg}}} \tn \hhline{>{\arrayrulecolor{DarkBackground}}-} \end{tabularx} \par\addvspace{1.3em} % That's all folks \end{multicols*} \end{document}